Yes, you can make a real CW RF transmitter without a spark gap, Tube or Transistor.
This site has many interesting experiments using homemade active devices.
Well, you will just have to go to the site yourself a see all the cool stuff. Also understanding these experiments is a rue education in Electronics, Chemistry, and Physics.
Cool Homemade Stuff etc.
I have saved this site in Archive.org for a permenate reference
Here is the Link.
https://web.archive.org/web/20190402042052/http://www.sparkbangbuzz.com/index.html
https://web.archive.org/web/20190402042052/http://www.sparkbangbuzz.com/index.html